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Determination of concentration profiles from diffusion experiments in liquid monotectic alloys by AAS

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Determination of concentration profiles from diffusion experiments in liquid monotectic alloys by AAS

Auteurs : RBID : ISTEX:216_1995_Article_BF00323087.pdf

Abstract

To study the transport behaviour in monotectic melts diffusion experiments have been carried out in the liquid homogeneous phase of aluminium-indium alloys. The penetration curves from mass transport experiments in capillaries with a ratio length/diameter >25 have been measured by Atomic Absorption Spectroscopy (AAS). The optimized quantitative measurement procedure for Al and In, the working parameters in the concentration range 0–50 mg/l and the observed interferences are described. By exact adjusting of sample and standard solutions, the concentrations of both elements have been determined with relative standard deviations less than 1%.

DOI: 10.1007/BF00323087

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<div type="abstract" xml:lang="eng">To study the transport behaviour in monotectic melts diffusion experiments have been carried out in the liquid homogeneous phase of aluminium-indium alloys. The penetration curves from mass transport experiments in capillaries with a ratio length/diameter >25 have been measured by Atomic Absorption Spectroscopy (AAS). The optimized quantitative measurement procedure for Al and In, the working parameters in the concentration range 0–50 mg/l and the observed interferences are described. By exact adjusting of sample and standard solutions, the concentrations of both elements have been determined with relative standard deviations less than 1%.</div>
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<abstract lang="eng">To study the transport behaviour in monotectic melts diffusion experiments have been carried out in the liquid homogeneous phase of aluminium-indium alloys. The penetration curves from mass transport experiments in capillaries with a ratio length/diameter >25 have been measured by Atomic Absorption Spectroscopy (AAS). The optimized quantitative measurement procedure for Al and In, the working parameters in the concentration range 0–50 mg/l and the observed interferences are described. By exact adjusting of sample and standard solutions, the concentrations of both elements have been determined with relative standard deviations less than 1%.</abstract>
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